I have been thinking about this too for a couple of days, my colour gets ashy during the darker months and the winter light here in the far north makes everything look even more cool toned which I kind of like but I would also like to have the option to make some changes during early spring.
I know that lemon, and other citrus I guess, can lighten the hair but I think that it might also cause dryness which can make hair more prone to damage (at least my hair). I have heard that honey can lighten the hair also but honey makes my hair dry too, maybe a "treatment" with chamomile and a teaspoon of honey and some drops of lemon could do the trick? I guess you have a lot of sunny days in Australia so maybe you could sit with your back to the sun and the hair out (with or without the rinse) for a while if you have the time? About the when and where I would say that it could work both before or after showering but that it would be best to wash out or rinse the hair with water afterwards and maybe conditioner if you use that or your favourite hair oil.
May I ask how you wash your hair? I have noticed that my hair looks darker and ashier when I use only baking soda (and an ACV rinse), I don't know why but even a friend of mine who doesn't care about hair at all asked me out of nowhere if I had toned it.
This post got a bit messy I suspect but I have a fever right now so if something is unclear just ask!
Edit: I have also read that cinnamon can lighten the hair but I don't know if it will remove the ashy tones in blonde hair or if it works best for brown hair.
Second edit: I just tried cinnamon and I do not recommend it if you have sensitive skin, maybe if you are careful and don't get it on the scalp/skin which I did - I got two grains on my forehead and got very red skin in circles around them, about three centimetres in diameter. I made a mixture of eggyolk, cinnamon and my regular washing conditioner and the other two ingredients I have never had a problem with. Didn't want to irritate my scalp so I rinsed it out after just five minutes so I don't think it did any difference on my haircolour, I'll have to wait until it dries.
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