I've done some hair sticks with polymer clay. I do polymer clay jewelry and came up with the idea of coating a stick (I used a wooden barbeque skewer stick cut to desired length) with polymer clay. I also did one with a cheap wooden sushi chopstick, but it ended up a bit too thick for my liking. For me perfect circumference would be somewhere in the middle of those two examples, so when you add the clay, it doesn't get too thick. Craft stores probably sell craft wood in different sizes, I would need to check that one day.
But the possibilities and choices of color and style are endless with polymer clay, and you can add all kinds of glitters and mica powders to clay as well. And when you wet sand and polish the baked stick it creates a very smooth surface. One could even use a glaze to get it really shiny but I didn't glaze mine because from my experience some glazes start to peel off when exposed to stuff like makeup, perfumes or hair spray etc.
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