Hi, kittenpajamas, and welcome to LHC!
Build-up is not the gunk on your scalp, it's product on your hair. It's not something you can see, but if your hair is misbehaving a good wash with a clarifying shampoo should be your first action. ACV rinses do not clarify.
If you've been using shampoo/conditioner containing silicones and haven't clarified you're bound to have build-up. Silicones ('cones) are not "bad", you just have to be aware of what they do, which is coat your hair. This is supposed to seal moisture in and make your hair look good, but the trouble is it also seals moisture
out and conceals the resulting damage. This is why, if you use 'cones, you need to clarify (using a proper clarifying shampoo, such as the one spidermom recommended) regularly. The SMT you did probably didn't work because it couldn't reach your strands due to build-up. You don't need to leave an SMT on overnight, by the way; even 5 minutes will make a difference.
V05 is excellent stuff, which is why so many of us use it. You don't have to spend a lot of money on products to get good results. In particular, look for the V05 "moisture milks" range of conditioners.
So clarify before you do anything else, and follow it with a good moisturising conditioner - basic SMT is ideal for this. Just conditioner, honey and aloe vera gel. Once you've done that you'll have a better idea of what you're dealing with. Oh, and if you
classify your hair for us we'll be able to help you better.
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